New electrolyte synthesis diagram for subsequent-gen fuel cells

Dr. Ho-Il Ji from the Hydrogen Vitality Provides Analysis Heart at the Korea Institute of Science and Technology (KIST, President Sang-Rok Oh), alongside with Professor Sihyuk Choi’s group from Kumoh National Institute of Technology, dangle made a groundbreaking constructing. They’ve developed a modern synthesis diagram that dramatically reduces the sintering temperature required for the densification means of the electrolyte in subsequent-generation high-effectivity protonic ceramic cells.

This innovation addresses the challenges faced by gift stable oxide cells (SOC) and paves the diagram for cost-effective, high-efficiency fuel cell and electrolysis operations.

In the realm of energy conversion gadgets, protonic ceramic cells (PCCs) dangle emerged as a modern innovation, the exercise of proton (hydrogen ion) transport rather than odd oxygen ions. This groundbreaking expertise permits enormously higher ionic conductivity, offering immense attainable for fuel cells and electrolyzers.

However, the manufacturing of PCC electrolytes has faced a vital hurdle in consequence of the requirement for sintering at extraordinarily high temperatures, main to degradation of the ion-conducting properties.

In a thrilling constructing, a research group has pioneered a brand fresh task for synthesizing electrolyte affords, aiming to beat this anguish. By synthesizing a powder containing two various compounds by low-temperature synthesis, the group successfully reduced the sintering temperature to 1,400°C with out the want for components. This leap forward no longer handiest addresses the field of electrolyte degradation but additionally paves the diagram for the commercialization of PCCs as extremely efficient and legitimate energy conversion gadgets.

The modern proton ceramic electrolyte produced by this modern task creates a dense membrane even at lower temperatures, enormously making improvements to the electrochemical properties of the cell. In exact proton ceramic cells, this electrolyte has demonstrated excellent proton conductance, reaching a excellent energy density of 950mW/cm² at 600°C—almost double that of latest cells in the marketplace.

The twin-section proton ceramic electrolyte produced by the low-temperature synthesis task shows enhanced sintering characteristics, enabling a reduce rate in the sintering temperature of archaic processes. Which means, the intrinsic properties of the electrolyte would possibly possibly be realized in the tool, making improvements to cell efficiency.
The twin-section proton ceramic electrolyte produced by the low-temperature synthesis task shows enhanced sintering characteristics, enabling a reduce rate in the sintering temperature of archaic processes. Which means, the intrinsic properties of the electrolyte would possibly possibly be realized in the tool, making improvements to cell efficiency. Credit ranking: Korea Institute of Science and Technology

This leap forward is poised to streamline processing time whereas concurrently making improvements to thermal steadiness and the final efficiency of ceramic electrolytes.

The research group is desirous to implement this cutting-edge task, harnessing accelerated sintering between the two compounds, to electrify sizable-home cells and pave the diagram for the commercialization of proton ceramic cells.

“This research has resolved the chronic sintering components in the manufacturing of proton ceramic cells. If sizable-home expertise is successfully developed, this is able to possibly allow efficient energy administration by inexperienced hydrogen manufacturing through electrolysis and pink hydrogen manufacturing by the exercise of waste warmth from nuclear energy vegetation,” said Dr. Ji of KIST.

Journal reference:

  1. Junseok Kim, Jiwon Yun, Wanjae Lee, Safe-Hyeong Kim, Puspendu Guha, Jin-Ha Hwang, Deok-Hwang Kwon, Sungeun Yang, Jong-Ho Lee, Kyung Joong Yoon, Ji-Won Son, Sahn Nahm, Sihyuk Choi, Ho-Il Ji, Twin-Section Response Sintering for Overcoming the Inherent Sintering Skill of Refractory Electrolytes in Protonic Ceramic Cells. Evolved Vitality Provides, 2024; DOI: 10.1002/aenm.202400787